Free Ebook Silane Coupling Agents, by E.P. Plueddemann
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Silane Coupling Agents, by E.P. Plueddemann
Free Ebook Silane Coupling Agents, by E.P. Plueddemann
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* Much progress has been made in the last 8 years in understanding the theory and practice of silane coupling agents. A major advance in this direction was the measurement of true equilibrium constants for the hydroly sis and formation of siloxane bonds. Equilibrium constants for bond reten tion are so favorable that a silane coupling agent on silica has a thousandfold advantage for bond retention in the presence of water over an alkoxysilane bond formed from hydroxy-functional polymers and silica. In practice, the bonds of certain epoxies to silane-primed glass resist debonding by water about a thousand times as long as the epoxy bond to unprimed glass. Oxane bonds of silane coupling agents to metal oxides seem to follow the same mechanism of equilibrium hydrolysis and rebonding, although equilibrium constants have not been measured for individual metal-oxygen silicon bonds. This suggests, however, that methods of improving bond retention to glass will also improve the water resistance of bonds to metals. of standard coupling agents with a hydrophobic silane or one Modification with extra siloxane cross-linking have improved the water resistance of bonds to glass and metals another hundredfold over that obtained with single coupling agents.
- Sales Rank: #3757391 in Books
- Published on: 1991-04-30
- Original language: English
- Number of items: 1
- Dimensions: 9.21" h x .69" w x 6.14" l, 1.25 pounds
- Binding: Hardcover
- 253 pages
Most helpful customer reviews
8 of 8 people found the following review helpful.
Classic text on this topic, a bit old, but essential reading
By Michael A. Kinsella
Excellent reference book. Essential reading for any chemist or student working in the the field of bonding polymers to glass. Assumes degree level chemistry, so not so accessible to engineers hoping to get background on sizing. Does not discuss micromechanics nor fiber/matrix interphase in mechanical terms. Main focus is bonding glass fibers to thermosetting resins, but also looks at thermoplastics, elastomers (not much detail) and Chapter 8 briefly covers various non composite applications such as water repellent surface treatments, silica packings of GLC (chromatography), etc. etc. Book shows it age in places, but well worth having on your bookshelf.
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